Wrapping up Metal–Organic Framework Crystals with Carbon Nanotubes

The presence of tetrazine units in the organic nodes UiO-68-TZCD controls formation ultrathin coatings single-wall nanotubes that decorate surface crystal. These crystal hybrids can be prepared straightforwardly one step and are extraordinarily respectful with properties framework for combination mesoporosity areas ≈4.000 m2 g−1, excellent stability water, conductivities at room temperature 4 × 10−2 S cm−1 even very low carbon weight contents (2.3 wt.%).